全文获取类型
收费全文 | 501篇 |
免费 | 13篇 |
国内免费 | 27篇 |
专业分类
安全科学 | 172篇 |
废物处理 | 27篇 |
环保管理 | 40篇 |
综合类 | 169篇 |
基础理论 | 24篇 |
污染及防治 | 26篇 |
评价与监测 | 19篇 |
社会与环境 | 8篇 |
灾害及防治 | 56篇 |
出版年
2023年 | 17篇 |
2022年 | 12篇 |
2021年 | 33篇 |
2020年 | 31篇 |
2019年 | 15篇 |
2018年 | 8篇 |
2017年 | 4篇 |
2016年 | 14篇 |
2015年 | 25篇 |
2014年 | 23篇 |
2013年 | 27篇 |
2012年 | 28篇 |
2011年 | 24篇 |
2010年 | 15篇 |
2009年 | 20篇 |
2008年 | 17篇 |
2007年 | 30篇 |
2006年 | 24篇 |
2005年 | 15篇 |
2004年 | 12篇 |
2003年 | 17篇 |
2002年 | 17篇 |
2001年 | 18篇 |
2000年 | 12篇 |
1999年 | 15篇 |
1998年 | 14篇 |
1997年 | 11篇 |
1996年 | 7篇 |
1995年 | 6篇 |
1994年 | 7篇 |
1993年 | 6篇 |
1992年 | 4篇 |
1991年 | 1篇 |
1990年 | 3篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1979年 | 1篇 |
1977年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有541条查询结果,搜索用时 15 毫秒
61.
火力发电行业主要气态污染物排放量计算方法研究 总被引:1,自引:0,他引:1
针对目前我国火力发电行业气态污染物排放量计算方法使用混乱的情况,根据欧盟《空气污染物排放清单指南》和美国《空气污染物排放因子汇编》,介绍了火电行业主要气态污染物排放量的实际测量及理论计算方法。提出我国火电行业应根据实际情况,选择实际测量、排放因子或经验公式等方法计算污染物排放量;使用排放因子方法计算SO2排放量时,应开展S元素转化率的研究;火电厂应增加燃料中N元素的分析,以利于NOx排放量的准确估算。 相似文献
62.
63.
19世纪是我国特大暴雨洪水发生期 总被引:1,自引:0,他引:1
本文用大量资料,论述了我国七个江河历史首位洪水均发生在19世纪。而且,洪水泛滥使得平原地区的水系迁移、湖泊淤缩极为严重。同时,存洪水年前后,伴随着一系列寒冷、干旱的气候异常现象。 相似文献
64.
选取冀南城市群为研究区,基于2012~2016年VⅡRS卫星数据热异常点产品,结合工业能源消耗量、工业废气排放量以及空气质量数据,利用统计分析和空间分析探讨热异常点辐射强度的变化规律及其与工业能源消耗、污染物排放之间的关系.结果表明,热异常点的辐射强度可以表征工业能源消耗量,并间接反映工业生产规模与污染排放水平.辐射强度越大,工业生产规模越大.辐射强度与工业SO2排放量呈较高的正相关,与NOx排放量呈中度线性相关.PM10、SO2及NO2浓度与工业能源消耗和热异常点辐射强度灰色关联度均较高.工业生产活动产生的污染物中,颗粒物对大气污染的贡献最高,其次为SO2.2012~2016年,邯郸、石家庄以及廊坊的工业生产空间分布呈逐年收缩聚集的趋势,保定和沧州的工业生产分别出现向南、向西迁移趋势. 相似文献
65.
The utilization of waste products as valuable materials was a technical imperative for waste management. In this study, the cost-effective attapulgite/carbon(APT/C) composite was developed for wastewater treatment using waste hot-pot oil as a carbon precursor through a facile one-step calcination process. The APT/C composite prepared at 300°C exhibited the excellent adsorption capacity and rapid equilibrium rate over a broad p H range for the removal of various pollutants. More importantly, the removal ratios of the composites toward Methyl Violet and tetracycline still remained 77.6% and 60.2% of the initial adsorption capacity after ten adsorption–regeneration cycles via a facile thermal regeneration strategy, respectively.Beyond all doubt, this research provided a feasible and economical way for the sustainable utilization of waste hot-pot oil in wastewater treatment, achieving the concept of disposal waste with waste and recycling. 相似文献
66.
67.
The pure decomposition behavior of 2,2′-azobis (isobutyronitrile) (AIBN) and its physical phase transformation were examined and discussed. The thermal decomposition of this self-reactive azo compound was explored using differential scanning calorimetry (DSC) to elucidate the stages in the progress of this chemical reaction. DSC was used to predict the kinetic and process safety parameters, such as self-accelerating decomposition temperature (SADT), time to maximum reaction rate under adiabatic conditions (TMRad), and apparent activation energy (Ea), under isothermal and adiabatic conditions with thermal analysis models. Moreover, vent sizing package 2 (VSP2) was applied to examine the runaway reaction combined with simulation and experiments for thermal hazard assessment of AIBN. A thorough understanding of this reaction process can identify AIBN as a hazardous and vulnerable chemical during upset situations. The sublimation and melting of AIBN near its apparent onset decomposition temperature contributed to the initial steps of the reaction and explained the exothermic attributes of the peaks observed in the calorimetric investigation. 相似文献
68.
Jen-Hao Chi Sheng-Hung WuJean-Claude Charpentier Yet-Pole IChi-Min Shu 《Journal of Loss Prevention in the Process Industries》2012,25(1):142-147
Hydrogen peroxide (H2O2), historically, due to its broad applications in the chemical industries, has caused many serious fires and explosions around the world. Its thermal hazards may also be incurred by an incompatible reaction with other chemicals, and a runaway reaction may be induced in the last stage. This study applied thermal analytical methods to explore the H2O2 leading to these accidents by incompatibility and to discuss what might be formed by the upset situations. Thermal hazard analysis contained a solvent, propanone (CH3COCH3, so-called acetone), which was deliberately selected to mix with H2O2 for investigating the degree of thermal hazard. Differential scanning calorimetry (DSC) and vent sizing package 2 (VSP2) were employed to evaluate the thermal hazard of H2O2. The results indicated that H2O2 is highly hazardous while mixed with propanone, as a potential contaminant. The time to maximum rate (TMR) was used as emergency response time in the chemical industries. Therefore, TMR of H2O2 was calculated to be 70 min for runaway reaction (after T0) and TMR of H2O2/propanone was discovered to be 27 min only. Fire and explosion hazards could be successfully lessened if the safety-related data are properly imbedded into manufacturing processes. 相似文献
69.
针对既有聚苯乙烯泡沫类外墙外保温系统的防火问题,在空气和氮气气氛下对非阻燃和阻燃型膨胀聚苯乙烯泡沫进行了热重分析。样品由10℃/min、20℃/min、40℃/min和50℃/min四个升温速率从室温加热至800℃。热分解动力学参数由Flynn-Wall-Ozawa(FWO)等转化率方法和多参数非线性回归方法(multivariate non-linear re-gression method)计算,结果表明六溴环十二烷(HBCD)阻燃剂可一定程度上提高EPS的热稳定性。EPS在空气和氮气气氛下热解可认为是单步反应。非阻燃聚苯乙烯泡沫在空气和氮气气氛下的热解过程可由自催化n阶反应机理描述。阻燃EPS在空气气氛下的热解机理为自催化n阶反应,在氮气气氛下则为n阶反应机理。基于动力学参数和反应机理,对聚苯乙烯泡沫在不同温度下的寿命进行了预测。 相似文献
70.
For lack of an extinguishing agent with high-efficiency, non-toxic and environmentally friendly, a new type of extinguishing agent was fabricated to solve such an urgent problem. In this study, the zinc borate (ZB) and ferrocene (Fe(Cp)2) were utilized as two additives for extinguishants to suppress combustion reaction and the toxicity of the tail gas was detected. The mass fraction of ZB corresponding to the optimal inhibitory effect was determined to be 0.5–1.5%, by contrast, the optimum interval of Fe(Cp)2 was detected as 0.5–1.0%. Similarly, with the increasing proportion of the two additives, the homologous inhibitory action was gradually weakened. From the perspective of thermogravimetric analysis (TGA), it was indicated that the ZB accelerated the pyrolysis process of the extinguishant, making its thermal decomposition process more thoroughly. Meanwhile, the differential scanning calorimetry (DSC) demonstrated that the decomposition efficiency was markedly improved when the amount of ZB was maintained at 0.5–1.5%. Besides, the tail gas tests were implemented to assess the extent of toxic and harmful properties. In terms of the carbon monoxide (CO) and carbon dioxide (CO2) generated, once the mass fraction of ZB and Fe(Cp)2 was less than 1.5% and 1.0% respectively, the concentration of CO and CO2 was distinctly lower than that without additives. Moreover, the inhibitory ability on nitrogen oxides (NOx) was enhanced when the mass fraction of the two additives was kept below 1.0%. The results confirmed that a more practical extinguishant was proposed and it can provide guidance for the application and development of extinguishants. 相似文献